Wednesday, October 26, 2011

John B. Townsend II: The Long, Hot Summer And Code Red Days

The once-dreaded idiomatic expression "the long, hot summer" regained a literal patina or shade of meaning during the summer months of 2011. Cities are no longer "aflame in the summer time," and even the venerable Farmers' Almanac predicted it would be a white-hot summer. Across these United States, it was the hottest summer in 75 years, and the second-warmest summer on record, the National Climatic Data Center has confirmed. It was also the fifth-hottest summer in the Northern Hemisphere since scientists began compiling such climatological records 132 years ago.

Well, you don't have to "know much about a science book," or global climate change, to realize our summers are hotter than ever before. Yet, there has been a significant reduction in the amount of pollution caused by automobiles in the Washington metro region. That's a major milestone, since the smog standards are now more stringent than ever before for the average concentrations of ozone at ground level over an eight-hour period.

This is vital and paramount because 1.5 million people who live and move and have their being in the Washington-Baltimore region fall within the sensitive groups impacted by unhealthy air quality. They suffer from heart and respiratory ailments, including asthma, emphysema and chronic bronchitis. So, whenever pollutants and/or high air temperatures in the region surpass the national standard for safe or healthy air quality, local officials declare such events "Code Red Days" or "Code Orange Days." When this occurs, agencies and the American Lung Association caution sensitive groups, including children and older adults, to avoid "prolonged outdoor exertion" and everyone else to "limit prolonged outdoor exertion."

Keep in mind, Washington (which really wasn't built on a swamp) sweltered in a protracted heat wave all summer long. But myth aside, the town had all the seeming of a primordial slough back in July. That's because July 2011 holds the distinction of being the "hottest month in recorded history" in Washington, D.C. As it turns out, July had 25 days where the mercury soared to 90 degrees or above. Warmer than your mother's oven on Thanksgiving morning, three of those days had Fahrenheit temperatures above 100 degrees. In contrast, June registered ten 90-degree days. During the sultry days of August, the region racked up 12 such days.

Yet by dint of the overall number of unhealthy ozone days, the metro area registered only two Code Red Air Quality Days and 19 Code Orange Air Quality Days during the sultriest days of summer. That's according to preliminary data compiled by the Metropolitan Washington Council of Governments (COG).

If records were meant to be broken, last year was the region's hottest summer ever. Even so, during the 2010 Ozone Season, the region recorded only three Code Red Air Quality Days as June turned to July, and then into August. "But on two of those days, only one out of 14 active air quality monitors indicated Code Red air quality, and on the third day only two monitors registered a violation," exults the Northern Virginia Transportation Alliance (NVTA).

The region also recorded 30 Code Orange Day during the dog days of the summer of 2011, according to the Clean Air Partners. However, on the "average Code Orange day nearly 80% of the region's monitors did not record a violation," the NVTA notes.

Compare that to the region's track record back in the summer of 1998, when we suffered from 6 Code Red Days and 49 Code Orange Days, according to data from the Clean Air Partners. Yet the clean air standard is higher now than it was in 1998. Still, the region had fewer unhealthy air days during 2010 and 2011, than it did a decade and a half ago.

In 1997, the Environmental Protection Agency (EPA) replaced the one-hour standard and set into place the eight-hour standard set at 84 parts per billion (ppb), explains Kyle Hosley of Clean Air Partners. In 2008, over the protests of some elected officials and business interests, the EPA actually tightened the smog standard -- the eight-hour National Ambient Air Quality Standard (NAAQS) for ground-level ozone -- setting it at 75 ppb.

To protect the health of the public and the environment, the EPA calculates the Air Quality Index (AQI) for five major air pollutants regulated by the Clean Air Act. These are: ground-level ozone, particle pollution (also known as particulate matter), carbon monoxide, sulfur dioxide, and nitrogen dioxide. Two of these pollutants -- ground-level ozone and airborne particles -- pose the greatest threat to human health.

Credit stronger environmental safeguards, and reductions in air pollution emissions, for clearing the air and for reducing the number of unhealthy ozone days in the Washington metro area and other parts of the country, scientists say. Though 35.4% of households in Washington, D. C. proper do not own a car, the region has just shy of four million registered vehicles. Under the mandates of the Federal Clean Air Act, those local vehicles, which are cleaner, are required to burn cleaner summer fuel blends designed to cut down on smog in the Washington metro area.

And it is working wonders. To further reduce tailpipe emissions, the nation's fleet of cars, pickup trucks, mini-vans and SUVs since 2004 has become 77 to 95 percent cleaner than older models, notes the EPA. As a result, automobile emissions are no longer the primary source of summertime ozone smog. Other factors have also dramatically improved air quality in the region, including the public's growing demand for cleaner-burning power plants, and other technological advances.

So here is the upshot. Overall, the number of "exceedance days" is decreasing across the region, although the ozone standard is more difficult to meet. The region is making great strides on this front, though much work remains to be done. Still, some Capitol Hill denizens have lost sight of this and there is a growing chorus in Congress to defund the EPA.

For a certain element in Washington and the states, the agency has been a b?te noire for more than four decades since its inception on December 3, 1970. Ever the red-headed stepchild in the minds of some, the agency, ironically, was the brainchild of President Richard Nixon. Yet the EPA has established national air quality standards and the program is improving the quality of life in the Washington metro area. This is as clear as the air we now breathe even on the days declared Code Red Air Quality Days and Code Orange Air Quality Days.

For all its huffing and puffing about the EPA, Congress should gaze a few blocks down North Capitol Street to the headquarters of the Metropolitan Washington Council of Governments (COG). It houses the offices of the Clean Air Partners. Yonder it will find over 2,900 businesses, employers, and individuals across the Washington-Baltimore region working in concert to reduce the number of unhealthy air days. They are registered as Clean Air Partner participants.

The empirical evidence stands. Air quality in the region has improved over the past decade, Clean Air Partners say. Instead of holding its breath until it's blue in the face, Congress should just exhale. And then inhale.

?

Source: http://www.huffingtonpost.com/john-b-townsend-ii/the-long-hot-summer-and-c_b_1007805.html

empire state of mind lyrics rex grossman carolina panthers arizona cardinals minnesota vikings chargers cake boss

Tuesday, October 25, 2011

Where are the iPad killers? (Digital Trends)

samsung-galaxy-tab-101-vs-ipad-2

When Apple announced the iPad in January 2010, a significant portion of the technology industry thought Steve Jobs had a flop on his hands. Although some greeted the iPad announcement with unbridled enthusiasm, many others shrugged the device off as merely a ?big iPhone.? Underpowered, overpriced and lacking must-have features like a camera, keyboard, and USB. Yet the iPad and its successor ?the iPad 2 have essentially defined the tablet computing industry. The crucial question for every tablet that?s come to market since has been ?why would someone buy this instead of an iPad?? So far, the most answer is usually ?no reason.?

So where are the iPad?s competitors, how did the iPad reach this level of success, and does the iPad actually have an Achilles heel competitors can exploit?

Where?s Android today?

The iPad?s domination of the tablet market is hard to underestimate, but some people try. Strategy Analytics recently published a report analyzing OS market share for tablets in the third quarter of 2011. It paints one of the rosiest pictures yet for iPad competitors, claiming Apple only had two thirds of the worldwide tablet market. That still seems like an unsurmountable lead, but Strategy Analytics noted that was down from 95.5 percent the year before, and that 26.9 percent of the global market had been claimed by Android tablets. That?s some 4.5 million Android units compared to Apple?s 11.1 million iPads.

That might be encouraging for iPad competitors? if it were true. Apple regularly discloses how many iPad units it has sold, so the 11.1 million figure for the quarter can be taken at face value. However, Strategy Analytics has admitted to GigaOm that its figure of 4.6 million Android tablets includes the number of units that have shipped, not sold; tablets sitting in stores and on warehouse shelves are counted the same way as iPads in customers? living rooms and book bags. Furthermore, Strategy Analytics included all sub-versions of Android in its totals, including devices running versions before the tablet-optimized Honeycomb. The report also tallied in the Barnes & Noble Nook Color e-reader, which can be converted to a full Android tablet by the technically inclined, but isn?t sold as one. In short, the survey essentially counts every non-smartphone Android-running device that can be vaguely construed as a tablet, and compares that figure to iPads people have actually bought.

GigaOm?s Kevin Tofel takes a shot at more accurate number for Android tablets, based on Android activation figures disclosed by Andy Rubin at Google?s Ice Cream Sandwich rollout placed against Android Market access figures. By that accounting, the number of Android 3.0 tablets currently in users? hands seems to be about 3.4 million.

That figure includes all Android 3.0 devices, however, not just tablets sold during the third quarter, so it can?t be compared directly with Strategy Analytics? figures. The first Android 3.0 device (the Motorola Xoom) went on sale in February 2011. During its most recent two quarters (a roughly equivalent period running from late March through late September ? we?ll give Android 3.0 a month?s head start), Apple sold 20.37 million iPads. That generously gives Android about 14 percent of the tablet market since the introduction of Android 3.0, considering just iPads and Android devices. The figure would be a bit lower if we figured in sales of tablets like the HP TouchPad, the RIM PlayBook, and Windows-based tablets?and if we included iPad sales from February.

Why haven?t Android tablets taken off?

Android would seem to have all the advantages over the iPad. Setting aside debates about the meaning of ?open? for the time being, Android devices are available from a variety of different manufacturers with designs designed to meet many different needs. Android tablets come in a variety of screen sizes and form factors, and in many cases offer screen resolution, graphics, and hardware specs that match or exceed the iPad. As a platform, Android tablets can be very diverse, where the iPad is famously one-size-fits all: Users? only real choices are the amount of built-in storage and whether they want 3G capability.

Apple wouldn?t have been able to launch the iPad successfully if the iPhone didn?t already have serious market momentum: Apple was not only able to leverage a vast pool of applications and an already-mature touch-centric mobile operating system for the iPad, but was also able to lock in suppliers. Apple famously maintains a strong lock on the worldwide market for the 9.7-inch displays used in the iPad. They?re made by Samsung and LG, and DisplayBank?found Apple snapped up 83 percent of all 9.7-inch displays made during May, or some 4.5 million units. (A small portion of the remainder went to the HP TouchPad.) Apple obviously doesn?t buy that many displays every month, but its orders clearly account for a huge portion of the market. Apple also has favorable arrangements with companies like Samsung to keep iPads flush with flash memory, and Apple?s new CEO Tim Cook is well-known for playing hardball with suppliers to keep Apple?s costs down, and suppliers have even complained Apple has strong-armed for low prices then cut their orders once a deal has been inked.

Motorola Xoom Family EditionThe upshot is that Apple, long accused of peddling overly expensive gear, is now in a position where it?s almost impossible for competitors to match Apple?s pricing on similarly-specced tablets. To be sure, some are trying: Motorola has just announced a forthcoming ?Family Edition? of its Xoom tablet for a suggested price of $380?that?s down from the initial $800 price tag on the original Motorola Xoom. And tablets like the Asus Eee Transformer and Acer Iconia have base prices as much as $100 less than an iPad?s starting price. But most competitors have little choice but to either match Apple?s pricing (a la Samsung), stick to smaller form factors (like 7-inch displays) to keep costs down, or dive for the lowest price point possible with purpose-built devices that just happen to run Android (a la the Nook Color).

Android fragmentation and the Android Market

Google has been working hard to make Android a serious competitor in the tablet arena, and the forthcoming Android 4.0 Ice Cream Sandwich release, which claims to do away with the distinction between phones and tablets, looks to be a step in that direction. There?s an almost tacit acceptance now that Android is basically equivalent to Apple?s iOS, but it doesn?t take long working with them both ? especially on tablets ? to see that?s often not yet true. Android sometimes offers stunning performance, but just as often stalls or hiccups for no apparent reason: Simple scrolling is usually great place to see the difference. Apple?s iOS offers remarkably consistent interface, even across many third-party apps, where Android continues to be a mishmash of styles and metaphors, and often labors under third-party patinas that make matters even more confusing for everyday users. In short, iOS was tuned for the iPad when it debuted, but with Android 3.0 Google struggled to shoehorn a smartphone operating system into tablets, and is still sweating many of the details. Android generally works, but it often doesn?t work all that great.

Android tablets have also suffered from fragmentation of the Android platform and in the Android market. iPads could run the vast majority of iPhone apps when they launched, and similarly Android tablets can theoretically run all kinds of Android apps. But the reality is much messier. Many Android games and apps are restricted to dual-core processors, and sometimes specific chips. Your tablet might be be able to run dual-core apps, but that doesn?t mean that it?ll run titles designed for Nvidia?s Tegra 2 processor. Being on Android alone isn?t enough. Android tablet users have also encountered apps that fail to scale correctly (or even run) on larger screen resolutions, and there?s almost no way to know if an app will cope with a larger screen size until you try it. And that?s leaving aside issues of Android versioning (how many consumers know if they?re running Froyo, Gingerbread, or Honeycomb?) and app support. It?s not unusual for major applications to debut with support for only a small subset of Android devices ? and sometimes (say with Minecraft) that?s all about marketing. When consumers buy an Android tablet, they?re not buying into the whole Android ecosystem: they?re buying into a hazy subset of it, and that?s leaving aside the issue of alternative application stores. The iPad is simpler: one store, and clear indications whether an app is incompatible.

How to kill the iPad?

Google is pressing the Android platform forward with Ice Cream Sandwich, and the next version of Android holds a great deal of promise. However, it?s not clear that Ice Cream Sandwich alone is going to make Android tablets compelling in the marketplace alongside the iPad. The question will still be ?Why by an Android tablet instead of an iPad?? For many consumers, Ice Cream Sandwich isn?t going to change the answer very much.

Instead, the way for Android tablets to gain marketshare against the iPad might be to take the path of the Barnes & Noble Nook and the forthcoming Kindle Fire: use the ?free and open? Android as a base platform for low-cost, purpose-built devices. For the Nook Color and the Fire, that?s based purely on media consumption (books and video), but as Android evolves it could make a compelling platform for gaming devices, navigation systems, home automation, social media tool, or other devices that we haven?t even imagined yet.

Amazon Kindle Fire - hand modeledOf course, the problem with relying on purpose-built Android devices like the Nook Color and Kindle Fire to bolster Android is that neither device sees Android as much of a feature. Nook Colors have to be tweaked to become full-fledged Android tablets, and the Kindle Fire basically considers Android?s benefit to buyers as a source for email apps: Android itself is buried under Amazon?s custom interface. But if Android wants to dominate the tablet market and become a ubiquitous platform, specialized products that redefine tablet computing might be the way to go.

After all, the iPad is designed as be a general purpose device. Historically, general purpose devices tend to be more expensive than specialized products, and don?t excel at specialized tasks. After all, you can take a Corolla onto a race track or out on a two-track dirt road? but it wouldn?t be your first choice.

The iPad?s current success is based on defining the tablet market: Right now, for most consumers, ?tablet? and ?iPad? are synonymous. But most iPad customers don?t use most of the iPad?s capabilities: instead, it?s mainly a Web browser, a video playback device, an email client, a social media tool, an ereader, or a gaming platform. That flexibility aids the iPad, but it would be difficult to recommend the iPad solely as an ereader, video viewer, or any one of those things, at least on a cost basis. By focusing doing particular tasks very well, Android tablets could gain market share by eliminating general-purpose features they don?t need and substantially undercutting the iPad?s price.

It?s just not very glamorous.

This article was originally posted on Digital Trends

More from Digital Trends

Source: http://us.rd.yahoo.com/dailynews/rss/personaltech/*http%3A//news.yahoo.com/s/digitaltrends/20111025/tc_digitaltrends/wherearetheipadkillers

rachel uchitel amerigo vespucci julio jones elizabeth warren coptic church steve bartman columbus day

At fundraisers, Obama says 60 percent of promises kept (Reuters)

LOS ANGELES (Reuters) ? President Barack racked up cash for his re-election campaign at fundraisers in Nevada and California on Monday, declaring that he had kept 60 percent of the promises he made as a candidate in 2008.

Obama is in the middle of a three-day swing through battleground states in the West, a trip that Republicans have blasted as evidence that he cares more about saving his own job than helping unemployed Americans.

Mixing official White House business with stops to raise funds, Obama -- who is far ahead of his rivals in campaign cash -- is working to expand the financial advantage he hopes to maintain next year.

As part of his message at one fundraiser, where some 40 donors each paid $35,800 to attend, Obama listed his accomplishments since entering office in 2009 and said he needed more time to finish what his administration had begun.

"A lot of the things that we promised we'd do, we've done," Obama said, citing healthcare reform and ending the "don't ask, don't tell" policy preventing gay men and women from serving openly in the U.S. military.

"I carry around a little checklist, and I think we've got about 60 percent of it done so far. And that's not bad for three years, because I need another five."

Obama, whose small audience included actor Will Smith and former basketball star Magic Johnson, touted an initiative he announced earlier to help struggling homeowners refinance their mortgages.

"That could free up billions of dollars for American consumers who can then shop and go to Will's movies, spend money at whatever business Magic has these days, and could help grow the economy overall," he said.

Obama held a second fundraiser in the Los Angeles area at the home of actress Melanie Griffith and actor Antonio Banderas. Tickets for the roughly 200 guests started at $5,000 a head.

At a fundraiser in Las Vegas, nearly 300 people paid between $1,000 and $35,800 to hear Democratic president draw a contrast between himself and the Republicans running to replace him in next year's election.

"The Republicans in Congress and the Republican candidates for president have made their agenda very clear," Obama said.

"They have two basic economic principles: first, tax cuts for the very wealthiest and the biggest corporations...Second is just about every regulation that's out there they want to get rid of -- clean air, clean water -- you name it."

Republicans charge that Obama's administration has instituted too many regulations that strangle businesses and hurt the economy. Former Massachusetts governor Mitt Romney, the frontrunner for the Republican presidential nomination, has pledged to repeal Obama's healthcare reform law if he prevails over Obama in 2012.

Source: http://us.rd.yahoo.com/dailynews/rss/obama/*http%3A//news.yahoo.com/s/nm/20111025/pl_nm/us_usa_campaign_obama_fundraising

slaughterhouse cypher last man standing gary johnson gary johnson jim thorpe pa jim thorpe pa

Pilot Brian Shul speaks tonight at pancreatic cancer fundraiser

SR-71 pilot Brian Shul, author of the acclaimed ?Sled Driver,? will share his inspiring story of being shot down in Vietnam and left for dead, only to go on to fly the top-secret Blackbird, considered the highest, fastest and most extraordinary aircraft ever built, at a fundraising dinner taking place tonight at Wings Over the Rockies Air & Space Museum.

Shul?s remarks are part of ?Wings of Hope,? a dinner that his sister, former Castle Pines Mayor Maureen Shul, is organizing on behalf of Denver affiliate of the Pancreatic Cancer Action Network, a national organization creating hope through research, patient support, community outreach and advocacy for a cure. The event begins with cocktails and a silent auction at 6 p.m. Tickets can be purchased by visiting www.pancan.org/wingsofhope

Maureen Shul, who remains a member of the Castle Pines city council, is staging the dinner in honor of her mother and brother, Victor, who both died of pancreatic cancer. Maureen remained at Victor?s side for the four years that he fought the disease; he died in 2009.

Five months after losing her brother, Maureen?s mother was diagnosed with pancreatic cancer, this in addition to the Alzheimer?s disease she had been diagnosed with eight years earlier. Blanche Shul passed away from pancreatic cancer three months after her diagnosis, never knowing that her son had succumbed to it, also.

Propelled by grief and a desire to honor her brother and mother, Maureen Shul says her goal for ?Wings of Hope? is to help raise awareness of and research dollars for pancreatic cancer. ?When pancreatic cancer barges into your family with no forewarning and little available information from which to draw upon, you are left with horrendously sobering statistics and little else,? Shul states.

?My family was stunned as to how little there was in the way of early diagnostic testing for pancreatic cancer,? she adds. ?Just as shocking, the five-year survival rate has remained unchanged at just six percent for the last 40 years due to detection tools and effective treatment still undeveloped. Despite the sobering statistics, just two percent of the National Cancer Institute?s federal research funding is allocated to pancreatic cancer.

?My desire is that Wings of Hope will raise awareness as well as research funding to mount a viable assault on this disease,? Shul says. ?When you suffer through losses this profound you are compelled to do something to honor your loved ones in ways that will hopefully result in more awareness and tools to help the many others whose lives have been or will be impacted by this horrific disease.?

Pancreatic cancer is the fourth leading cause of cancer death in the United States. In 2010, over 43,000 Americans were diagnosed with pancreatic cancer and nearly 37,000 died. The Pancreatic Cancer Action Network is the national organization creating hope in a comprehensive way through research, patient support, community outreach and advocacy for a cure.

Joanne Davidson: 303-809-1314 or jdavidson@denverpost.com. Also, @GetItWrite on Twitter

Source: http://blogs.denverpost.com/davidson/2011/10/22/pilot-brian-shul-speaks-tonight-at-pancreatic-cancer-fundraiser/8348/

tv guide listings buddy holly buddy holly baylor prime numbers prime numbers lithium

Monday morning KO: A reminder of Matt Mitrione?s power

With Matt Mitrione taking on Cheick Kongo this Saturday at UFC 137, it's a good time to take a look back at how Mitrione ended his last fight. Here is a snippet of his bout with Christian Morecraft at UFC on Versus 4.

This fight will be Mitrione's toughest test yet. He is undefeated, with all of his fights have? in the UFC after a career in the NFL. Will Mitrione handle Kongo's striking? Tell us in the comments or on Facebook.

Source: http://sports.yahoo.com/mma/blog/cagewriter/post/Monday-morning-KO-A-reminder-of-Matt-Mitrione-?urn=mma-wp8479

cerebral palsy hitch alice cooper segway namibia namibia 9 11 pictures

Monday, October 24, 2011

Panetta criticizes North Korea for 'reckless' acts

U.S. Secretary of Defense Leon Panetta meets with service members at the U.S. Yokota Air Base in Fussa, west of Tokyo, Monday, Oct. 24, 2011. Panetta arrived in Japan Monday on the second leg of a weeklong Asia tour. (AP Photo/Koji Sasahara)

U.S. Secretary of Defense Leon Panetta meets with service members at the U.S. Yokota Air Base in Fussa, west of Tokyo, Monday, Oct. 24, 2011. Panetta arrived in Japan Monday on the second leg of a weeklong Asia tour. (AP Photo/Koji Sasahara)

U.S. Secretary of Defense Leon Panetta speaks to service members at the U.S. Yokota Air Base in Fussa, west of Tokyo, Monday, Oct. 24, 2011. Panetta arrived in Japan Monday on the second leg of a weeklong Asia tour. (AP Photo/Koji Sasahara)

U.S. Secretary of Defense Leon Panetta speaks to service members at the U.S. Yokota Air Base in Fussa, west of Tokyo, Monday, Oct. 24, 2011. Panetta arrived in Japan Monday on the second leg of a weeklong Asia tour. (AP Photo/Koji Sasahara)

U.S. Secretary of Defense Leon Panetta speaks to service members at the U.S. Yokota Air Base in Fussa, west of Tokyo, Monday, Oct. 24, 2011. Panetta arrived in Japan Monday on the second leg of a weeklong Asia tour. (AP Photo/Koji Sasahara)

(AP) ? U.S. Defense Secretary Leon Panetta on Monday lashed out at North Korea for "reckless and provocative" acts and criticized China for a secretive expansion of its military power.

Panetta, who arrived at this U.S. air base on the second leg of a weeklong Asia tour, spoke out about North Korea and China in an opinion piece published Monday by Japan's Yomiuri newspaper before his arrival.

He wrote that Washington and Tokyo share common challenges in the Asia-Pacific. "These include North Korea, which continues to engage in reckless and provocative behavior and is developing nuclear weapons and ballistic missiles, which pose a threat not just to Japan but to the entire region," he wrote.

If any changes are made to U.S. forces in the Pacific, he said, it would be to "strengthen" their presence.

"We are not anticipating any cutbacks in this region," he told several dozen U.S. and Japanese troops standing in front of huge side-by-side American and Japanese flags. "If anything, we're going to strengthen our presence in the Pacific ? and we will."

He offered no examples of such moves. The U.S. now has about 47,000 troops in Japan and about 28,000 in South Korea ? remnants of World War II and the Korean War. Panetta's strong language comes as U.S. and North Korean officials gather in Geneva for talks that Washington says are aimed at determining whether Pyongyang is serious about returning to nuclear disarmament talks.

Japan also worries about North Korea and is one of five countries that have jointly tried to persuade the North Koreans to cap and reverse their nuclear arms program. The other four are the U.S., China, Russia and South Korea.

Panetta also criticized China.

"China is rapidly modernizing its military," he wrote in Monday's opinion piece, "but with a troubling lack of transparency, coupled with increasingly assertive activity in the East and South China Seas."

He wrote that Japan and the U.S. would work together to "encourage China to play a responsible role in the international community."

A day earlier, in Bali, Indonesia, Panetta offered more positive remarks about China. He told reporters that Beijing deserved praise for a relatively mild response to a $5.8 billion US arms sale to Taiwan announced in September.

Panetta is not visiting China on this trip, his first to Asia since becoming Pentagon chief in July.

Associated Press

Source: http://hosted2.ap.org/APDEFAULT/386c25518f464186bf7a2ac026580ce7/Article_2011-10-24-Panetta-Asia/id-e936bae1706f44f6bece20e3aed9b79e

urban meyer cj wilson zodiac killer baked alaska baked alaska battlefield 3 review battlefield 3 review

Giant flakes make graphene oxide gel

Friday, October 21, 2011

Giant flakes of graphene oxide in water aggregate like a stack of pancakes, but infinitely thinner, and in the process gain characteristics that materials scientists may find delicious.

A new paper by scientists at Rice University and the University of Colorado details how slices of graphene, the single-atom form of carbon, in a solution arrange themselves to form a nematic liquid crystal in which particles are free-floating but aligned.

That much was already known. The new twist is that if the flakes ? in this case, graphene oxide ? are big enough and concentrated enough, they retain their alignment as they form a gel. That gel is a handy precursor for manufacturing metamaterials or fibers with unique mechanical and electronic properties.

The team reported its discovery online this week in the Royal Society of Chemistry journal Soft Matter. Rice authors include Matteo Pasquali, a professor of chemical and biomolecular engineering and of chemistry; James Tour, the T.T. and W.F. Chao Chair in Chemistry as well as a professor of mechanical engineering and materials science and of computer science; postdoctoral research associate Dmitry Kosynkin; and graduate students Budhadipta Dan and Natnael Behabtu. Ivan Smalyukh, an assistant professor of physics at the University of Colorado at Boulder, led research for his group, in which Dan served as a visiting scientist.

"Graphene materials and fluid phases are a great research area," Pasquali said. "From the fundamental point of view, fluid phases comprising flakes are relatively unexplored, and certainly so when the flakes have important electronic properties.

"From the application standpoint, graphene and graphene oxide can be important building blocks in such areas as flexible electronics and conductive and high-strength materials, and can serve as templates for ordering plasmonic structures," he said.

By "giant," the researchers referred to irregular flakes of graphene oxide up to 10,000 times as wide as they are high. (That's still impossibly small: on average, roughly 12 microns wide and less than a nanometer high.) Previous studies showed smaller bits of pristine graphene suspended in acid would form a liquid crystal and that graphene oxide would do likewise in other solutions, including water.

This time the team discovered that if the flakes are big enough and concentrated enough, the solution becomes semisolid. When they constrained the gel to a thin pipette and evaporated some of the water, the graphene oxide flakes got closer to each other and stacked up spontaneously, although imperfectly.

"The exciting part for me is the spontaneous ordering of graphene oxide into a liquid crystal, which nobody had observed before," said Behabtu, a member of Pasquali's lab. "It's still a liquid, but it's ordered. That's useful to make fibers, but it could also induce order on other particles like nanorods."

He said it would be a simple matter to heat the concentrated gel and extrude it into something like carbon fiber, with enhanced properties provided by "mix-ins."

Testing the possibilities, the researchers mixed gold microtriangles and glass microrods into the solution, and found both were effectively forced to line up with the pancaking flakes. Their inclusion also helped the team get visual confirmation of the flakes' orientation.

The process offers the possibility of the large-scale ordering and alignment of such plasmonic particles as gold, silver and palladium nanorods, important components in optoelectronic devices and metamaterials, they reported.

Behabtu added that heating the gel "crosslinks the flakes, and that's good for mechanical strength. You can even heat graphene oxide enough to reduce it, stripping out the oxygen and turning it back into graphite."

###

Rice University: http://media.rice.edu

Thanks to Rice University for this article.

This press release was posted to serve as a topic for discussion. Please comment below. We try our best to only post press releases that are associated with peer reviewed scientific literature. Critical discussions of the research are appreciated. If you need help finding a link to the original article, please contact us on twitter or via e-mail.

This press release has been viewed 31 time(s).

Source: http://www.labspaces.net/114525/Giant_flakes_make_graphene_oxide_gel

austin tx us postal service trey songz wcc hugh jackman theme steiner ranch